Sunrise gets too much credit. Before the Sun clears the horizon, its light already reaches air above the observer, where scattering redirects some of that radiation toward the ground. Darkness retreats by proxy. What looks like daylight arriving ahead of schedule is the atmosphere making a hidden source visible through its effects, rather than through its disk.
The air deserves closer attention. Because Earth's surface curves away beneath the atmosphere, elevated layers can receive sunlight while the ground below remains within the planet's shadow. Molecules do the scattering. In Rayleigh scattering, air molecules scatter shorter visible wavelengths more strongly than longer ones, helping explain why blue spreads across a sky illuminated by sunlight. Dawn complicates that picture. When sunlight follows a long, slanting path through the atmosphere, much of its blue light is scattered out of the direct beam, leaving warmer colors near the horizon. Light takes detours, too. Multiple scattering, in which light changes direction more than once, also contributes to twilight illumination.
Dawn refuses a fixed timetable. Its duration depends on latitude and season because these determine the angle at which the Sun's apparent path approaches the horizon. Local conditions edit the view. Clouds, airborne particles and obstructions can alter the brightness or colors an observer sees, even when the Sun occupies the same position below the horizon. Sunrise is merely an entrance. By the time the disk appears, the sky has already spent a quiet interval announcing something the ground could not yet see.